I think I've figured this out now. I made video podcasts using typepad and then my feeds are managed with feedburner. The feeds were always fine and I could download the video attachments from the feed in a browser or from feedburner just fine. But, iTunes kept giving me an unknown error 505 when I downloaded. This has turned out to be the spaces in the file name. iTunes doesn't URL encode the links to the media. If I url encode the file name in the link to the media in the blog post then iTunes works fine. So, if your file is "http:ssssssss/WXS 3.m4p" then change it to "http:ssssss/WXS%203.m4p" and then it's fine.
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